A new theory offers a strategy to channel damaging heat away from next-generation nano-electronics.
Putting a cone-like “chimney” between the graphene and nanotube all but eliminates a barrier that blocks heat from escaping.
Heat is transferred through phonons, quasiparticle waves that also transmit sound. Both graphene and carbon nanotubes consist of six-atom rings, which create a chicken-wire appearance, and both excel at the rapid transfer of electricity and phonons.
But when a nanotube grows from graphene, atoms facilitate the turn by forming heptagonal (seven-member) rings instead. Scientists have determined that forests of nanotubes grown from graphene are excellent for storing hydrogen for energy applications, but in electronics, the heptagons scatter phonons and hinder the escape of heat through the pillars.
Connecting cones
Researchers at Rice University discovered through computer simulations that removing atoms here and there from the two-dimensional graphene base would force a cone to form between the graphene and the nanotube. The geometric properties of the graphene-to-cone and cone-to-nanotube transitions require the same total number of heptagons, but they are more sparsely spaced and leave a clear path of hexagons available for heat to race up the chimney.
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“Our interest in advancing new applications for low-dimensional carbon—fullerenes, nanotubes, and graphene—is broad,” says theoretical physicist Boris Yakobson, professor of materials science and nanoengineering and a professor of chemistry.
“One way is to use them as building blocks to fill three-dimensional spaces with different designs, creating anisotropic, nonuniform scaffolds with properties that none of the current bulk materials have. In this case, we studied a combination of nanotubes and graphene, connected by cones, motivated by seeing such shapes obtained in our colleagues’ experimental labs.”
Tunable options
The researchers tested phonon conduction through simulations of free-standing nanotubes, pillared graphene, and nano-chimneys with a cone radius of either 20 or 40 angstroms. The pillared graphene was 20 percent less conductive than plain nanotubes. The 20-angstrom nano-chimneys were just as conductive as plain nanotubes, while 40-angstrom cones were 20 percent better than the nanotubes.
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“The tunability of such structures is virtually limitless, stemming from the vast combinatorial possibilities of arranging the elementary modules,” says Alex Kutana, a research scientist and coauthor of the study. “The actual challenge is to find the most useful structures given a vast number of possibilities and then make them in the lab reliably.
“In the present case, the fine-tuning parameters could be cone shapes and radii, nanotube spacing, lengths and diameters. Interestingly, the nano-chimneys also act like thermal diodes, with heat flowing faster in one direction than the other,” he says.
Coauthors are from Rice and the Air Force Research Laboratory in Dayton, Ohio. The research appears in the Journal of Physical Chemistry C.
The Air Force Office of Scientific Research and its Multidisciplinary University Research Initiative supported the research.
Source: Rice University
